Zincate wouldnāt work too well here, since electroless zincate plating makes for a very thin coating. But if people want an electroplated zinc coating, it would work well.
Something like:
- Deanodized
- Copper
- Nickel
- Zinc
- Silver(+ min qty needed)
Gold salts(+ min qty needed)
Iāll post my progress in a few minutes to show you what Iāve made.
I wonāt make any progress this week though because of exams.
Aluminum oxidizes almost instantly in air. Thatās why welding it is so darn hard. Just to test, submerge some aluminum and sand it with sand paper. Leave it in the solution, and fire up the rig. Hopefully the sanded area will plate. If this works, then you can always brainstorm on a chemical de-oxidizer method for the next go round.
I can easily dissolve any copper into solution using a galvanic cell process at high concentrations(8-10g/L), but I specifically need Pyrophosphate as a weak base for the zinc to be etched away, but the copper to stick.
Sodium cuprate(copper dissolved in sodium hydroxide) does etch the zinc, and plates copper, but sodium hydroxide attacks the aluminium, meaning you get a gap between the aluminium and copper, and copper does not stick.
If I get can get Pyrophosphate, then Iāll easily be set for making copper plated lights.
I donāt have any. All I can do is drop an email to a guy on youtube that knows his chemistry. I sent a short email to Cody at Codyās Lab to see if the topic piqueās his interest. If so maybe he can join the conversation about making some, or do a project on his channel in the future about the topic.
Yeah, thanks a lot, but I donāt think Cody is going to be interested by this.
Anyway, Iāve dropped emails to suppliers in Canada and some on Alibaba to see if I can get small quantities of pyrophosphate(1-3kgs) for a small batch for electroplating.
Fair enough. I for one would love to learn more about this electroplating process. And as you said info is scarce. Seems like a perfect challenge for an educational YouTuber focused on chemistry.
Actually, I think someone like Cody would be very interested in learning how to electroplate aluminium.
I mean Iāve discovered tons of stuff in this process:
1. How to make sulfuric acid using Epsom salt using a galvanic cell electrolysis.
2. How to make sodium zincate for electroless plating of aluminium using electrolysis, or for higher concentrations, reverse galvanic cell electrolysis.
3. How to make copper sulfate using electrolysis, or for higher concentrations, galvanic cell electrolysis.
4. Making sodium cuprate as strike copper plating(not flash copper) on non-aluminium parts.
Iām also currently in the process of making a shiny copper sulfate solution using small quantities of ammonium hydroxide as a surfactant, tiny quantities of sodium hydroxide as an emulsifier, and hydrochloric acid for a small chloride solution etch.
Say, do you guys think I should make another thread for this?
This is an electrolysis thread, so a de-anodizing tutorial and electroplating thread would be great.
Because Iād rather make a thread in which I put up tutorials on how to:
- De-anodize effectively and safely .
- Prepare diverse copper/nickel plating solutions, and other materials if deemed necessary.
And most importantly, how to recycle plating materials for safe disposal.
That last one is especially important.
Before disposing of my sodium hydroxide solution, I actually thought about running my electroplating setup in reverse using a carbon rod to get the copper out of the solution.
And I managed to get a pure sodium hydroxide along with some pure copper.
Sorry to revive the old thread but its quite hard to find people with a similar interest in this chemistry.
Iāve done some testing here involving copper deposition on aluminum based on a video by Simpletronic.
Uses only ferric chloride (muriatic acid, steel wool, hydrogren peroxide), copper sulphate and salt.
Iāve achieved some minor success here. The shiny portion is good copper that sticks properly on the aluminum. When put into a copper electroplating bath, that area is plated fine, although the surrounding area is dirty brown that only accumulates clumps of copper goo. Need to repeat some test why that particular area is so successful. I suspect I will need to sand, clean, lye dip, rinse to achieve minimal contamination.