My charger do not charge LiIon to 4.2V, is it faulty?

Then you aren’t going to be happy since there are many “opinions” on those numbers. IMO, and in my own practice, I try to keep the voltage above 3.0v at all times and generally above 3.2v. There is VERY little capacity under 3.0v and the volts drop precipitously after that making it a slippery slope. There just is not a lot of good reason to push that far unless you are in an emergency situation. Why bother?
Once you go under 2.5 it gets dicey. Below 2.0 you are likely getting into damage area.

You don’t get immediate problems from over discharge, you get problems from charging AFTER over discharge and the damage it may incur.

I have tested a lot of lights and have found most commonly some cutoff point is around 2.6-2.8, which is why I was wondering. I often wonder why it’s usually about this voltage. I understand there isn’t a real consensus, but I wonder why that number is common.

It’s probably/mostly ‘safe’. That does not mean it’s optimal. Just look at the voltage drop on HKJ’s discharge graphs. Your choice.

Thanks HKJ for the effort put in here for us. Lets hope everyone’s DMM’s read accurately. :slight_smile:

I finally got a charger that charges to 4.2V, i suspect the ML-10X chargers are just made with components with loose tolerances because they finish charging from 4.04-4.11V, battery tested immediately off the charger.

Its interesting to note the voltage drops slightly as soon as removed, i suppose this is not well covered on BLF (add to the li ion thread :wink: ), so my 4.20V charger right off the charger must mean its charging to 4.22ish volts. I’m not going to complain, after living with 4.04V for years i’m happy to get a full charge.

Thanks for posting this thread HKJ :beer:

I did some tests once with batteries that came of at around 4.2v versus 4.17v (Nitecore I2 and Opus 3100 respectively) and from memory the difference was about 1.8% when I discharged them on my Accucel 6. Wouldn’t be useful or noticeable in real life usage for me.

This thread needs to be sticky’ed…

I have created a setting for my MC3000, with termination at 4.25V and 50mA, newer batteries come out at 4.20V, and drops to ~4.17V a couple hours later. But I don’t think there is any real benefit by doing so other than pleasing the absurd need of achieving exactly 4.20V.

It’s great to have articles written by someone that everyone trusts, keep going hkj, and thanks for the effort :slight_smile:

Another informative HKJ thread.

Opinions and metaphors can be interesting.

But it’s immensely more valuable to have conclusions that are supported by concrete facts and measurements.

Thanks for the excellent and informative write-up HKJ
:beer:

very informative post, thanks HKJ for your effort :slight_smile:

HKJ, thanks a lot for putting this down in a nice post for reference.

It was much needed. Ought to be stickied.

That would be good, and thanks for this one.

So that’s how you test charging voltage. Thanks for doing this guide, I’m getting my Fluke out right now.

Thank you!

Hi again, HKJ.

As always, thanks for your posts. They are really interesting.

Keeping in mind the information shown on this post, and the information shown on this old post, ( Charger settings ), are these sentences right?

Please confirm them for clarity sake.

1) Charging Li-ion cells to 4,1V means cells will have more lifetime, but less energy.

2) Charging Li-ion cells to 4,25V means cells will have less lifetime, but more energy.

3) Termination current high will make voltage drop after termination high.

4) Termination current low will make voltage drop after termination low.

5) Charging a cell to 4,2V with low current termination will give more performance than charging the same cell to 4,2V with high current termination.

6) The best possible charge to obtain maximum performance from a Li-ion cell is to charge it to 4,25V, and a very low termination current. (Forget about cell lifetime).

And some questions:

It is really interesting to go to 0,025A termination current, or even lower in big capacity cells (forget about charge times) or it doesn´t worth it?

Do you recomend to modify termination current setting, depending on the capacity of the cell?

For example:

5000mAh cells -> 0,125A termination current.
4000mAh cells -> 0,1A termination current.
3000mAh cells -> 0,075A termination current.
2000mAh cells -> 0,05A termination current.
1000mAh cells -> 0,025A termination current.

Again, thank you very much for your work.

Why would you want to charge to 4.25v? Are you that desperate for a tiny smidgen of performance you probably can’t even quantify without pretty good tools and knock a good percentage of your battery life off?

How does capacity correlate with charge voltage for lithium ion batteries?“:Charge voltage experiments with lithium ion batteries showing how capacity varies with charge voltage and higher cycle live with lower charge voltage

Thanks for the link, very useful and interesting.

Answer: to obtain maximum performance. I know doing this will cause shorter lifetime, but performance is performance.

Why drag race cars engines have this setup? For maximum performance. It doesn´t matter if it lasts for 2 or 4 miles, the most important is to perform as better as possible in the first mile and win the competition.

Answer2: don´t worry, I won´t charge my batteries to 4,25V. I preffer to extend their lifetime.

I sometimes wonder about 4.35v batteries. How much is that ACTUALLY a superior/different chemistry, and how much is ‘hot rodding’ the battery at the expense of shortening it’s life?

Hi again.

After reading SkyRC MC3000 charger manual, I have one more doubt:

(Regarding Termination, http://www.skyrc.com/index.php?route=product/product/download&download_id=149 , page 13/22 )

The termination current of the CV-phase of Li-Ion battery charging algorithm, also of NiZn. When
reaching TARGET VOLT, e.g. 4.20V, this option will hold the voltage constant while automatically
reducing the current down to the specified value before it terminates the charging routine. A high
termination current serves battery health but will not charge the full battery capacity. The
parameter defaults to 10% of C.CURRENT, an industrial standard. “Zero” means an ever
decreasing charging current: not good for your patience or battery but allows to produce quasiconstant
4.200V battery voltage if that’s what you’re after. OFF means no CV-phase once the
target voltage has been reached.

That means high termination current is good for batteries lifetime?