Don’t do this inside your house or garage, take it outside away from anything that could burn your house down. Don’t do this while sleeping.
Don’t try to fully charge (8,4V) any configuration of these bastard cells.
When you connect 2 cells in parallel, then they need to be equal in voltage to +/-10 mV. If not then you can have a big spark and huge current flowing between them. Cells in parallel always try to keep themselves at the same voltage. So if you keep charging to 8.4, then the smaller capacity cell of a parallel group will get overcharged.
When you connect cells or groups of cells in series, then they should have the same capacity and be balanced to the same voltage also. If not then one group (with lower capacity) will fill quicker and get overcharged while trying to bring the other group up to the final voltage. Cells in series always have the same current flowing thru them.
If in the example, you put a 2Ah and 3Ah in parallel, then it doesn’t make a 5 Ah—it makes a 4Ah capacity group. When you charge this you must use coulomb counting (current x time) to determine and control when it it “full” with 4Ah.
But a 3Ah cell that only has 2Ah worth of energy will not have the same voltage as a full 2Ah cell. So i don’t think mixing different size (capacity) cells in parallel is a good idea.
The best way to do this is to drain all the cells to the same voltage, e.g. 2.8V. Then connect all of them in parallel and let them sit on the bench to equalize and balance the voltage. Then connect in any series/parallel configuration you want, but you can only charge to add 4Ah worth of energy to the pack. Charging must regulate by current and capacity, not by voltage. Measure the voltage after completing the 4Ah charge, then this will be your reference Upper Voltage to never exceed when charging.
Without a BMS then YOU are the battery management system.
@kennybobby, everything you said is correct except these bits about different capacities in parallel:
“But a 3Ah cell that only has 2Ah worth of energy will not have the same voltage as a full 2Ah cell. So i don’t think mixing different size (capacity) cells in parallel is a good idea.”
That’s not true. The 3Ah cell will charge at the same relative speed as the 2Ah one, just at a higher current.
Putting cells in parallel just makes for a larger capacity cell.
“If in the example, you put a 2Ah and 3Ah in parallel, then it doesn’t make a 5 Ah—it makes a 4Ah capacity group. When you charge this you must use coulomb counting (current x time) to determine and control when it it “full” with 4Ah.”
Take your 5Ah paralleled cell and connect a load to draw 4 Amps.
After 1 hour the electrolyte of the 2Ah cell is depleted of ions, but the 3Ah cell is still 1/3 full.
As you continue with the load the 2Ah cell will continue to supply current, but it will not be from Li+ ion transfer but rather from elemental copper being pulled out of the anode current collector. This is operating in the dendrite growth region and the cell will be permanently damaged.
This is the reason for bottom balancing this oddball configuration before connection and charging based upon the smaller cell, such that both cells will be depleted at the same time. The chain is only as strong as the weakest link.