I haven’t tried this myself but according to all that I have read is they do not catch fire except in very rare instances, which I only find one video after the fire. But I read it can happen in rare instances. 
This video shows one catching fire, when these guys throw it in a fire.
This one, they shoot a nail in it.
They have a pretty flat discharge curve even at high current loads.
This is a Lifepo4 chemistry not a Lipo, they are the safest of all lithium cells.