It doesn’t sound like an issue that “recovering” can fix. If your charger really put 4500mAh in to an 18650 cell it sounds like there could be some sort of internal short. Leave it unconnected and see if the voltage drops a lot. If there is an internal short it will keep dropping. In any case, based on the info you’ve given it doesn’t seem like a good cell.

Edit: what is recovering anyway? My understanding is that when people say recovering they mean charging an over-discharged cell with a low current until a typical smart charger recognizes it as a Li ion cell.