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The question is, will your vest operate on the higher voltage. 4 cells Li-ion moderate charge over 16v
A 3s / li-ion full charge 12.6v , will the vest run at the lower voltage 9v when almost totally discharged.
Yes LiPo4 cells match up to 12v way better, but they are twice as heavy, and capacity per size is usually half. If you go with Li-ion make sure you use quality everything, don’t want a battery incident with a vest strap on you .