Hi Barkuti
The material of the material is different, which leads to the different charging voltage.
The advantages of LifePo4 battery is High Cycle Life (1500-2000 cycle life), high temperature resistance and safe working at 60 degrees, so it is used in outdoor solar light, of course, many electric vehicles in China are also lithium ion batteries with LiFepo4 batteries(because the high cycle life)
The advantages of li-ion battery are high capacity and good low temperature resistance.
Below 0 degrees in winter, lithium ion performs better than Lifepo4