Is 4.0V on a lithium battery really 80% charge?

I have not explained well, i meant for normal everyday use i charge to 4V.
I tend to not use my high power lights much so they can be at 80% for weeks or rarely months for the rarely used lights.
My most used light is the Moon RC2 which has built in charging, it charges at 1A and has a 2.2Ah battery so i charge it for 1.5H from low voltage warning giving me about 75%ish.

This is incorrect.
Risk of overdischarge is mitigated by low voltage warning on most modern flashlights. Charging to less than 100% just gives reduced runtime. But storage at over 80% accelerates capacity fade.
I am using almost 10 year old 18650s that have over 95% of their original capacity.