This is how I do it, a little OCD here he he he 
I tape a meter stick to a wall and measure the hotspot size of the original setting for future comparison
Then I remove shims and measure hotspot with the reflector sitting bare at the MPCB (You might want to use Kapton tape to avoid shorting the reflector to the wires of the led. Measure hotspot on the meter stick, Compare Did it get bigger, smaller?
Then add shims of several thickness and measure hotspot on wall, until I find the best one.
Then comes the centering, sometimes I have a centering disk shim and just grind down to the desired thickness using a micrometer and sandpaper, install and done!
Sometimes I have to center it by eye, a little tedious but worth it, look directly to the led die (Hopefully you turned the light off first :bigsmile: ) and eyeball the distance from each corner of the die to the reflector wall make sure all are about the same distance.
After you got as centered as possible, turn light on on lowest mode and go to a wall get really close, like 30cm from the wall or less and you will notice a clover leaf light pattern on the wall (Hope this makes sense) look at each leaves they should be the same size like a + sign, simmetrical if you see all leaves the same size then you are at the exact center, sometimes you have to open the light and do very very small adjustments to the led, I small screwdrivers to gently and carefully push the led or mpcb to the side, until I have perfect focus.
I sometimes tailstand the light and rotate it looking at the corona, it should look simetrical, if it has more corona spill to one side you need to push the led to the other side just a hair or less, take the sides of the led die as reference for adjusting.
Hope this helps and makes sense.
AlexGT