80 seconds is specific to my hob so not a generic thing, could be quite a difference on yours. And i’m going from memory from what i was doing a couple of years ago, i have it written down somewhere but that 80 seconds well may actually be 120 seconds instead of the 1min 20 seconds i’ve remembered it as 
The cast iron pan would be fine, if you measure the temp in the pan it doesn’t matter what it’s made of really.
My hob is an old electrical one that has a lot of residual heat, hence having to allow for the temp still increasing once it’s been turned off. I use a 4” aluminium camping pan, it makes little difference to the temp because of the hob. I would guess a 4” cast iron one wouldn’t make too much difference but a large cast iron skillet would likely slow down the rate of temp increase and as my hob is on max i couldn’t increase it, which wouldn’t be ideal i can’t see it making much difference to me as a hobbyist.
If you have a more instant hob, such as infrared or induction, the cast iron may help control and maintain the heat slightly better that alu, and take a bit longer to cool down afterwards which would be better for the LED.
The soldering temperature recommendations are in LED spec sheets, for example a standard XP-G2 spec sheet: https://cree-led.com/media/documents/XLampXPG2.pdf
If you look at p32 in this one it shows a graph of the temp/time recommended for reflowing, takes a bit of time to match the numbers to the markers on the graph but once done it makes sense.
As for multi reflows, it depends on your speed and preperation but i’ve done triple boards comfortably without rushing. I miiight be able to do a board with 6 LEDs but i would need to work out how to prolong the pan staying at reflow temp, mine cools off too quickly.
My main focal points were on keeping the LED’s temp shock to a minimum by not heating it too quickly, and staying below it’s max recommended temp, which is why i used a thermometer rather than guesswork. I just wanted to know i hadn’t cooked the LED so i didn’t have to factor it in as possibility when troubleshooting a build.
Remember, folks on here do reflows with butane torches and soldering irons heating the MCPCB directly which would indicate a lot tolerance in the process, so anything even close the manufacturers specs should be fine.
I also remember one reflow (i purposely ignore the other couple :person_facepalming: ) where i forgot to heat the LED with the MCPCB so flowed a cold LED straight onto a hot MCPCB, it’s still working fine.